Hess
Background: There are many reactions for which direct measurement of the enthalpy reaction is difficult, the hydration of magnesium sulfate being such a reaction. In these cases it is often possible to determine the enthalpy of reaction by direct measurements on more accessible related systems and then applying Hess’ Law.Aim: to determine the change in enthalpy for the hydration of magnesium sulfate using Hess’ Law. Hypothesis: It looks like there are being more bonds formed than broken in this reaction, therefore, I think the change in enthalpy will be exothermic. - Temperature of the surroundings (this should not effect our experiment because it will be carried out in a polystyrene cup). - Air pressure (will have no effect on our experiment as it should not change during the short time our experiment will take.) - Temperature of the water (there will be an error with the thermometer) - Mass of MgSO4 and MgSO4•7H2O (error on the electronic balance) - Specific Heat Capacity (we are using the specific heat capacity of water) - Volume of Water – this is the controlled variable, as we will use the same amount of water in each experiment.
= 1641.46J/15.498g n = m ÷ Mr The theoretical answer for the endothermic reaction (MgSO4 + H2O à Mg2+ + SO42- + H2O) is –84kJmol-1, and the theoretical answer for the exothermic reaction (MgSO4•7H2O + H2O à Mg2+ + SO42- + 7H2O + H2O) was 16kJmol-1. 2. Accurately weigh out about 7.5 grams of anhydrous magnesium sulfate.
Some topics in this essay:
MgSO4•7H2O Error,
MgSO4 Error,
SULFATE Temperature,
H2O MgSO4•7H2O,
Container Method,
Mass H2O,
Practical Background,
Variables Temperature,
+ h2o,
Volume Water,
magnesium sulfate,
Mass MgSO4,
enthalpy change,
mgso4 +,
+ 7h2o,
mg2+ + so42-,
∆t =,
h2o à,
à mg2+,
so42- +,
+ so42-,
+ so42- +,
h2o à mg2+,
à mg2+ +,
+ h2o à,
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Approximate Word count = 1341
Approximate Pages = 5 (250 words per page double spaced)
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