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Chemical Equilibrium

Outline: Chapter 12 Gaseous Chemical Equilibrium

A. Equilibrium between liquid and gaseous water:

1. Chemical reactions involving gases are carried out in closed containers resemble in many ways the H2O(l)«H2O(g) system.

2. The reactions are reversible; the reactions are not completely consumed.

3. At equilibrium both forward and reverse reactions take place at the same rate.

4. Where gaseous chemical equilibrium are involved more than one gaseous substance is present. For example:

The equilibrium mixture contains two gaseous products (C and D) and two gaseous reactions (A and B).This is called partial equilibrium.

- The part of the total pressure in a gas mixture that can be attributed to a particular component. The partial pressure of a component may be found by multiplying the total pressure by the mole fraction. (each species that is Pc,PD,PA,and PB)

A. NO2 is formed by decomposition of the part of N2O4.

1.At first this is the only reaction taking place, as soon as the NO2 is formed the reverse reaction can occur:


The HCL formed removes oxide films from metals to be soldered. In certain equilibrium system at 400°C, 12.0g of NH4Cl is present; the partial pressure of NH3 and HCL are 3.0 atm.

3. The reciprocal rule shows when the numerator and denominator are inverted.

Some topics in this essay:
Introduction Equilibrium, Constant Table, Chatelier”s Principle, Mass H2O, Expression Equilibrium, N2O4 N2O4g«2NO2g, Establishment Equilibrium, PNO22 PN2O4, System N2O4g, Ex CO2g, partial pressure, equilibrium constant, equilibrium system, equilibrium partial, total pressure, chemical equilibrium, equilibrium partial pressure, 3´10-2 3´10-2, system equilibrium, 9´10-6 9´10-6, 3´10-4 3´10-4, h2 « cog, co2g + h2, partial pressure products, liquids solids appear,

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Approximate Word count = 956
Approximate Pages = 4 (250 words per page double spaced)


  

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