... electron transfer reaction.G* is the activation barrier that has to be overcome and is the -reorganisation energy-. The fundamental equation for the rate in the Marcus model derives from the Arrhenius and Eyring rate equation: k = e(-?G*/ kT) (9) Energy Reaction coordinate 13 where is the frequency of a vibration corresponding to the number of attempts per unit time to ascend the barrier. is a transmission ... ...

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