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Acids, Bases & Salts



             Zn (s) + H2SO4 (aq) à H2 (g) + ZnSO4 (aq).
             Acids release hydrogen in water solutions. When an acid dissolves in water, the acid ionizes, releasing both hydrogen ions and ions of a nonmetal or nonmetallic polyatomic ion. Thus, when hydrochloric acid is dissolved in water, the acid ionizes, forming hydrogen ions and chloride ions, as shown in the following equation:.
             HCl (aq) à H+ (aq) + Cl1- (aq).
             Other examples:.
             H2SO4 (aq) à 2 H+ (aq) + SO42- (aq).
             H3PO4 (aq) à 3 H+ (aq) + PO43- (aq).
             Special example:.
             HC2H3O2 (aq) ß -> H+ (aq) + C2H3O21- (aq) .
             Note the use of the double arrow in the ionization of acetic acid. We know that acetic acid is a weak acid. The smaller arrow pointing to the right indicates that the change to the right (ionization) is relatively small. This means that, in a solution of acetic acid, we have a large number of acetic acid molecules and few hydrogens and few acetate ions. .
             Thus acids are defined as substances that release hydrogen ions in solution. It is these H+ (aq) that are responsible for the properties of acids. .
             .
             How Acids are Prepared: .
             Acids may be prepared when certain gases, related to acids, are dissolved in water and when certain salt compounds, again related to acids, are allowed to react with sulfuric acid. .
             CO2 (g) + H2O (l) à H2CO3 (aq) carbonic acid .
             2 NaCl (s) + H2SO4 (aq) + heat à 2 HCl (g) + Na2SO4 (aq) .
             Uses of Acids: .
             Sulfuric acid is the chemical most widely used in industry. Sulfuric acid is also used to make other acids such as hydrochloric and nitric acid because the boiling point of sulfuric acid is higher that that of other acids. This allows the acid being produced to be distilled and collected separately from the starting material. .
             Sulfuric acid is also used to remove the surface oxide layers on metals (pickling) before the metals are coated with materials that prevent rusting.


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