and monatomic oxygen into molecular oxygen (O2).
In volcanic eruptions, the sulfate aerosols released are a .
natural cause of ozone depletion. The hydrolysis of N2O5 on .
sulfate aerosols, coupled with the reaction with chlorine in HCl, .
ClO, ClONO2 and bromine compounds, causes the breakdown of ozone. .
The sulfate aerosols cause chemical reactions in addition to .
chlorine and bromine reactions on stratospheric clouds that .
destroy the ozone.8.
Some ozone depletion is due to volcanic eruptions. Analysis .
of the El Chichon volcanic eruption in 1983 found ozone .
destruction in areas of higher aerosol concentration (Hofmann and .
Solomon, "Ozone Destruction through Heterogeneous Chemistry .
Following the Eruption of El Chichon"). They deduced that the .
"aerosol particles act as a base for multiphase reactions leading .
to ozone loss."9 Chlorine and bromine cooperates with .
stratospheric particles such as ice, nitrate, and sulfate to .
speed the reaction. Sulfuric acid produced by eruptions enhances .
the destructiveness of the chlorine chemicals that attack ozone. .
Volcanically perturbed conditions increase chlorine's breakdown .
of ozone. Also, chlorine and bromine react well under cold .
temperatures 15-20 kilometers up in the stratosphere where mos.
of the ozone is lost. This helps explain why there is less ozone .
in the Antarctic and Arctic polar regions.10, 11.
The Antarctic ozone hole is the largest. A 1985 study .
reported the loss of large amounts of ozone over Halley Bay, .
Antarctica. The suspected cause was the catalytic cycles .
involving chlorine and nitrogen.12.
Halons, an especially potent source of ozone depleting .
molecules, are used in fire extinguishers, refrigerants, chemical .
processing. They are composed of bromine, chlorine, and carbon. .
Most of the bromine in the atmosphere originally came from .
halons. Bromine is estimated to be 50 times more effective than .
chlorine in destroying ozone.13 .
Insect fumigation, burning biomass, and gasoline usage all .